In this study, there are three proton-conducting membranes were studied. They are based on the complex of poly-1-vinyl-1,2,4-triazole and phenol-2,4-disulfonic acid which were synthesized in several stoichiometric ratios. The highest proton conductivity value corresponded to the PVTPDSA membrane (20:80% wt.) - 5.98 · 10-2 S/cm
proton-conducting membranes, fuel cell, poly-1-vinyl-1,2,4-triazole, phenol-2,4disulfonic.
1. Kreuer K.D. On Solids with Liquid like Properties and the Challenge To Develop New Proton Conducting Separator Materials for Intermediate-Temperature Fuel Cells // Chem. Phys. Chem. 2002. Vol. 3. № 9. P. 771-775. 2. Schuster M.F.H., Meyer W. H., Schuster M., Kreuer K.D., Toward a New Type of Anhydrous Organic Proton Conductor Based on Immobilized Imidazole // Chemistry of Materials. 2004. Vol. 16. № 2. P. 329-337. 3. Wainright J.S.,Wang J.T., Weng D., Savinell R.F., Litt, M.J. Acid-Doped Polybenzimidazoles: A New Polymer Electrolyte // Journal of The Electrochemical Society. 1995. Vol. 142. № 7. P. 121-125. 4. Schuster M.F.H., Meyer W.H. Advance in Fuel Cells // Annual Review of Materials Research. Res. 2003. Vol 33. № 33. P. 233-240. 5. Smitha B., Sridhar S., Khan A.A. Solid polymer electrolyte membranes for fuel cell applications - a review // Journal of Membrane Science. 2005. Vol. 259. № 1. P. 10-26.
2. Kreuer K.D. On Solids with Liquid like Properties and the Challenge To Develop New Proton Conducting Separator Materials for Intermediate-Temperature Fuel Cells // Chem. Phys. Chem. 2002. Vol. 3. № 9. P. 771-775. 2. Schuster M.F.H., Meyer W. H., Schuster M., Kreuer K.D., Toward a New Type of Anhydrous Organic Proton Conductor Based on Immobilized Imidazole // Chemistry of Materials. 2004. Vol. 16. № 2. P. 329-337. 3. Wainright J.S.,Wang J.T., Weng D., Savinell R.F., Litt, M.J. Acid-Doped Polybenzimidazoles: A New Polymer Electrolyte // Journal of The Electrochemical Society. 1995. Vol. 142. № 7. P. 121-125. 4. Schuster M.F.H., Meyer W.H. Advance in Fuel Cells // Annual Review of Materials Research. Res. 2003. Vol 33. № 33. P. 233-240. 5. Smitha B., Sridhar S., Khan A.A. Solid polymer electrolyte membranes for fuel cell applications - a review // Journal of Membrane Science. 2005. Vol. 259. № 1. P. 10-26.
